{"created":"2025-09-05T07:20:15.369670+00:00","id":2000015,"links":{},"metadata":{"_buckets":{"deposit":"74ec851e-ebc6-4b13-ade4-6486a5cf58df"},"_deposit":{"created_by":13,"id":"2000015","owners":[13],"pid":{"revision_id":0,"type":"depid","value":"2000015"},"status":"published"},"_oai":{"id":"oai:kit.repo.nii.ac.jp:02000015","sets":["1753926516427:1753929991454:1753936243499"]},"author_link":[],"item_30002_access_rights4":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_30002_alternative_title1":{"attribute_name":"Alternative Title","attribute_value_mlt":[{"subitem_alternative_title":"複核ブリッジ型二配座亜鉛/カルボキシレート錯体によって活性化された硫黄架橋ゴムの特性に関する研究","subitem_alternative_title_language":"ja"}]},"item_30002_creator2":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorAlternatives":[{"creatorAlternative":"MIYAJI, Kosuke","creatorAlternativeLang":"en"}],"creatorNames":[{"creatorName":"宮地, 皓佑","creatorNameLang":"ja"}]}]},"item_30002_date11":{"attribute_name":"Date","attribute_value_mlt":[{"subitem_date_issued_datetime":"2021-03-25","subitem_date_issued_type":"Issued"}]},"item_30002_date_granted32":{"attribute_name":"Date Granted","attribute_value_mlt":[{"subitem_dategranted":"2021-03-25"}]},"item_30002_degree_grantor33":{"attribute_name":"Degree Grantor","attribute_value_mlt":[{"subitem_degreegrantor":[{"subitem_degreegrantor_language":"ja","subitem_degreegrantor_name":"京都工芸繊維大学"}],"subitem_degreegrantor_identifier":[{"subitem_degreegrantor_identifier_name":"14303","subitem_degreegrantor_identifier_scheme":"kakenhi"}]}]},"item_30002_degree_name31":{"attribute_name":"Degree Name","attribute_value_mlt":[{"subitem_degreename":"博士（工学）","subitem_degreename_language":"ja"}]},"item_30002_description9":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"To reveal the characteristics of sulfur cross-linking of rubber, a combination of modern approaches such as time-domain nuclear magnetic resonance spectroscopy, atomic force microscopy, in situ time-resolved Fourier-transform infrared spectroscopy, zinc K-edge X-ray absorption fine structure spectroscopy, and simultaneous time-resolved wide-angle X-ray scattering/tensile measurement were subjected. This thesis aims to provide some characteristics of sulfur cross-linking reaction via dinuclear bridging bidentate zinc/carboxylate complexes, and to make clear relationships between the structures and mechanical properties of the networks formed via the complexes.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_30002_dissertation_number30":{"attribute_name":"Dissertation Number","attribute_value_mlt":[{"subitem_dissertationnumber":"甲第989号"}]},"item_30002_file35":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","displaytype":"detail","filename":"D1-0989_y1.pdf","filesize":[{"value":"56.8 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"label":"内容の要約","objectType":"summary","url":"https://kit.repo.nii.ac.jp/record/2000015/files/D1-0989_y1.pdf"},"version_id":"2cdf6ad4-24ae-46f8-a24e-ab214b901ee2"},{"accessrole":"open_access","displaytype":"detail","filename":"D1-0989.pdf","filesize":[{"value":"173.1 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"label":"内容・審査結果の要旨","objectType":"abstract","url":"https://kit.repo.nii.ac.jp/record/2000015/files/D1-0989.pdf"},"version_id":"5f87c194-2909-4c7b-8f58-c47843a786f8"}]},"item_30002_language12":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_30002_resource_type13":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"doctoral thesis","resourceuri":"http://purl.org/coar/resource_type/c_db06"}]},"item_30002_subject8":{"attribute_name":"Subject","attribute_value_mlt":[{"subitem_subject":"Isoprene rubber","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Ethylene-propylene-diene monomer rubber","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Sulfur cross-linking","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"1H Time-domain nuclear magnetic resonance spectroscopy","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Atomic force microscopy","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Zn K-edge X-ray absorption fine structure","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Simultaneous time-resolved wide-angle X-ray scattering/tensile measurement","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_30002_title0":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_title":"Study on Characteristics of Sulfur Cross-Linking of Rubbers Activated by Dinuclear Bridging Bidentate Zinc/Carboxylate Complexes","subitem_title_language":"en"}]},"item_title":"Study on Characteristics of Sulfur Cross-Linking of Rubbers Activated by Dinuclear Bridging Bidentate Zinc/Carboxylate Complexes","item_type_id":"40002","owner":"13","path":["1753936243499"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-08-08"},"publish_date":"2024-08-08","publish_status":"0","recid":"2000015","relation_version_is_last":true,"title":["Study on Characteristics of Sulfur Cross-Linking of Rubbers Activated by Dinuclear Bridging Bidentate Zinc/Carboxylate Complexes"],"weko_creator_id":"13","weko_shared_id":-1},"updated":"2026-01-21T05:29:42.817979+00:00"}